Synthesis of haminol-A and haminol-B, polyenic alarm pheromones of Cephalaspidean molluscs

被引：9

作者：

Alvarez, R ^{[1
]}

de Lera, AR ^{[1
]}

机构：

[1] Univ Vigo, Dept Quim Fis & Quim Organ, Vigo 36200, Spain

来源：

TETRAHEDRON-ASYMMETRY | 1998年 / 9卷 / 17期

关键词：

D O I：

10.1016/S0957-4166(98)00324-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two stereocontrolled palladium-catalyzed cross-couplings of I-alkenyl boronic acids and aryl/alkenyl halides (the Suzuki-Miyaura reaction) are the key steps in an enantioselective approach to the polyene fragment of haminols A and B, alarm pheromones isolated from Haminoea navicula, a Cephalaspidean Opisthobranch mollusc. Chirality rested on the use of (S)-propylene oxide as the starting material. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：3065 / 3072

页数：8

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