Synthesis and reactivity of air-stable n-heterocyclic carbene gold(I) bis(trifluoromethanesulfonyl)imidate complexes

被引：203

作者：

Ricard, Louis

Gagosz, Fabien ^{[1
]}

机构：

[1] Ecole Polytech, Synth Organ Lab, F-91128 Palaiseau, France

[2] Ecole Polytech, Lab Heteroelements & Coordinat, F-91128 Palaiseau, France

来源：

ORGANOMETALLICS | 2007年 / 26卷 / 19期

关键词：

D O I：

10.1021/om7006002

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A study concerning the synthesis of new N-heterocyclic carbene gold(I) complexes using the bis(trifluoromethanesulfonyl)imidate moiety (Tf2N-) as a weakly coordinating counteranion is described. These new air-stable (NCH)AuNTf2 complexes are convenient to prepare, stoe, and handle and proved to be active in a range of gold(I)-catalyzed transfortnations.

引用

收藏

页码：4704 / 4707

页数：4

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