Efficient N,N-dimethylformamide extraction of endohedral metallofullerenes for HPLC purification

被引：46

作者：

Ding, JQ ^{[1
]}

Yang, SH ^{[1
]}

机构：

[1] HONG KONG UNIV SCI & TECHNOL,DEPT CHEM,KOWLOON,HONG KONG

来源：

CHEMISTRY OF MATERIALS | 1996年 / 8卷 / 12期

关键词：

D O I：

10.1021/cm960318j

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A new and efficient extraction method using DMF (N,N-dimethylformamide) was developed to concentrate endohedral metallofullerenes. This single-step extraction method obtained a solution containing 5-15% endohedral metallofullerenes and strongly discriminated against the dominant C-60, C-70, and higher empty fullerenes in raw soot. This highly selective extraction procedure substantially reduced sample loading in the HPLC isolation for a given volume of sample injection. The efficiency of our separation method is demonstrated by the isolation of the endohedral metallofullerene Ce@C-82.

引用

页码：2824 / 2827

页数：4

共 24 条

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