High-resolution spectrum of the 3 nu(1) band of cyanoacetylene obtained via infrared/infrared double resonance

被引：9

作者：

Gambogi, JE ^{[1
]}

Kerstel, ERT ^{[1
]}

Yang, XM ^{[1
]}

Lehmann, KK ^{[1
]}

Scoles, G ^{[1
]}

机构：

[1] PRINCETON UNIV, DEPT CHEM, PRINCETON, NJ 08544 USA

来源：

JOURNAL OF MOLECULAR SPECTROSCOPY | 1996年 / 175卷 / 01期

关键词：

D O I：

10.1006/jmsp.1996.0022

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

The 3v(1) band of cyanoacetylene has been recorded with 0.0005 cm(-1) resolution using sequential infrared/infrared double resonance excitation. Rotational levels from 0 less than or equal to J' less than or equal to 6 were measured and used to calculate v(0), B', and D'(J). The spectrum is slightly perturbed, with its features showing fractionation into two or three lines due to the onset of intramolecular vibrational energy redistribution. (C) 1996 Academic Press, Inc.

引用

收藏

页码：198 / 202

页数：5

相关论文

共 18 条

[1] EQUILIBRIUM GEOMETRY OF HC3N [J].

BOTSCHWINA, P ;

HORN, M ;

SEEGER, S ;

FLUGGE, J .

MOLECULAR PHYSICS, 1993, 78 (01) :191-198

[2] ROTATIONAL SPECTRA OF C-13 AND N-15 ISOTOPIC SPECIES OF CYANOACETYLENE [J].

CRESWELL, RA ;

WINNEWISSER, G ;

GERRY, MCL .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1977, 65 (03) :420-429

[3] MOLECULAR-BEAM ELECTRIC RESONANCE STUDY OF THE GROUND AND EXCITED-STATES OF CYANOACETYLENE [J].

DELEON, RL ;

MUENTER, JS .

JOURNAL OF CHEMICAL PHYSICS, 1985, 82 (04) :1702-1704

[4] INTRAMOLECULAR VIBRATIONAL DYNAMICS OF DIACETYLENE AND DIACETYLENE-D(1) VIA EIGENSTATE-RESOLVED OVERTONE SPECTROSCOPY [J].

GAMBOGI, JE ;

PEARSON, RZ ;

YANG, XM ;

LEHMANN, KK ;

SCOLES, G .

CHEMICAL PHYSICS, 1995, 190 (2-3) :191-205

[5] EIGENSTATE RESOLVED INFRARED/INFRARED DOUBLE-RESONANCE SPECTROSCOPY OF THE 3-NU(1) OVERTONE BAND OF 1-PROPYNE - INTRAMOLECULAR VIBRATIONAL-ENERGY REDISTRIBUTION INTO A CORIOLIS-COUPLED BATH [J].

GAMBOGI, JE ;

KERSTEL, ERT ;

LEHMANN, KK ;

SCOLES, G .

JOURNAL OF CHEMICAL PHYSICS, 1994, 100 (04) :2612-2622

[6]

HALL RR, 1984, THESIS RICE U

[7] HIGH-ENERGY VIBRATIONAL-STATES OF CYANOACETYLENE - VARIATIONAL AND PERTURBATIVE ANALYSIS OF AN ANHARMONIC NORMAL MODE [J].

HUTCHINSON, JS .

JOURNAL OF CHEMICAL PHYSICS, 1985, 82 (01) :22-30

[8]

Kerstel E. R. Th., 1991, Journal of Physical Chemistry, V95, P8282, DOI 10.1021/j100174a050

[9] DIRECT DECONVOLUTION OF EXTENSIVELY PERTURBED SPECTRA - THE SINGLET TRIPLET MOLECULAR EIGENSTATE SPECTRUM OF PYRAZINE [J].

LAWRANCE, WD ;

KNIGHT, AEW .

JOURNAL OF PHYSICAL CHEMISTRY, 1985, 89 (06) :917-925

[10] DIRECT DECONVOLUTION OF EXTENSIVELY PERTURBED SPECTRA - THE SINGLET TRIPLET MOLECULAR EIGENSTATE SPECTRUM OF PYRAZINE - COMMENT [J].

LEHMANN, KK .

JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (19) :7556-7557