Study of a heteropolyanion-doped poly(5-amino-1-naphthol) film electrode and its catalytic activity

被引：26

作者：

Pham, MC ^{[1
]}

Bouallala, S ^{[1
]}

Le, LA ^{[1
]}

Dang, VM ^{[1
]}

Lacaze, PC ^{[1
]}

机构：

[1] CNST, HANOI, VIETNAM

来源：

ELECTROCHIMICA ACTA | 1997年 / 42卷 / 03期

关键词：

poly(5-amino-1-naphthol); heteropolyacids;

D O I：

10.1016/S0013-4686(96)00239-3

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

A phosphomolybdic anion-doped poly(5-amino-1-naphthol) [poly(5-NH2-1-NAP)/PMo12] has been prepared by electrochemical polymerization of 5-amino-1-naphthol in aqueous 0.5 M H2SO4 containing PMo12O403- anions. The doped films were characterized by in situ FTIR spectroscopy and XPS analysis. The film-coated electrode was very stable upon potential cycling in acid; its catalytic effect on the reduction of chlorate anions was studied. Copyright (C) 1996 Elsevier Science Ltd

引用

收藏

页码：439 / 447

页数：9

相关论文

共 25 条

[1] TRANSPORT AND KINETICS IN MODIFIED ELECTRODES [J].

ALBERY, WJ ;

HILLMAN, AR .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1984, 170 (1-2) :27-49

[2]

ALBERY WJ, 1980, J ELECTROANAL CHEM, V107, P37, DOI 10.1016/0368-1874(80)80059-1

[3] CATALYSIS OF ELECTROCHEMICAL REACTIONS AT REDOX POLYMER ELECTRODES - KINETIC-MODEL FOR STATIONARY VOLTAMMETRIC TECHNIQUES [J].

ANDRIEUX, CP ;

DUMASBOUCHIAT, JM ;

SAVEANT, JM .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1982, 131 (JAN) :1-35

[4] KINETICS OF ELECTROCHEMICAL REACTIONS MEDIATED BY REDOX POLYMER-FILMS - IRREVERSIBLE CROSS-EXCHANGE REACTIONS - FORMULATION IN TERMS OF CHARACTERISTIC CURRENTS FOR STATIONARY TECHNIQUES [J].

ANDRIEUX, CP ;

SAVEANT, JM .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1982, 134 (01) :163-166

[5] KINETICS OF ELECTROCHEMICAL REACTIONS MEDIATED BY REDOX POLYMER-FILMS - NEW FORMULATION AND STRATEGIES FOR ANALYSIS AND OPTIMIZATION [J].

ANDRIEUX, CP ;

DUMASBOUCHIAT, JM ;

SAVEANT, JM .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1984, 169 (1-2) :9-21

[6] KINETIC-BEHAVIOR TO BE EXPECTED FROM OUTER-SPHERE REDOX CATALYSTS CONFINED WITHIN POLYMERIC FILMS ON ELECTRODE SURFACES [J].

ANSON, FC .

JOURNAL OF PHYSICAL CHEMISTRY, 1980, 84 (25) :3336-3338

[7] POLYPYRROLE AND POLY(N-METHYLPYRROLE) FILMS DOPED WITH KEGGIN-TYPE HETEROPOLYANIONS - PREPARATION AND PROPERTIES [J].

BIDAN, G ;

GENIES, EM ;

LAPKOWSKI, M .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1988, 251 (02) :297-306

[8]

Chastain J., 1992, HDB XRAY PHOTOELECTR, V40, P221

[9] SURFACE DERIVATIZATION OF HYDROXYL FUNCTIONAL ACRYLIC COPOLYMERS FOR CHARACTERIZATION BY X-RAY PHOTOELECTRON-SPECTROSCOPY [J].

DICKIE, RA ;

HAMMOND, JS ;

DEVRIES, JE ;

HOLUBKA, JW .

ANALYTICAL CHEMISTRY, 1982, 54 (12) :2045-2049

[10]

DILKS A, 1981, ELECT SPECTROSCOPY T, V4