New heterocyclic precursors for thermal generation of reactive, electron-rich 1,2-diaza-1 3-butadienes

被引：39

作者：

Boeckman, RK ^{[1
]}

Ge, P ^{[1
]}

Reed, JE ^{[1
]}

机构：

[1] Univ Rochester, Dept Chem, Rochester, NY 14627 USA

来源：

ORGANIC LETTERS | 2001年 / 3卷 / 23期

关键词：

D O I：

10.1021/ol0165645

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] The preparation and thermolysis of new stable heterocyclic precursors of 1,2-diaza-1,3-butadienes is described. The resulting reactive diazadienes are trapped in situ with N-phenyldiazamaleimide. The effect of precursor structure on the temperature at which the diazadienes are generated is discussed.

引用

页码：3647 / 3650

页数：4

共 31 条

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Boeckman, RK
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[J]. ORGANIC LETTERS, 2001, 3 (23) : 3651 - 3653

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