Direct observation of the benzyl radical and the benzyl anion within cation-exchanged zeolites. A nanosecond laser study

被引：15

作者：

Cozens, FL ^{[1
]}

Ortiz, W ^{[1
]}

Schepp, NP ^{[1
]}

机构：

[1] Dalhousie Univ, Dept Chem, Halifax, NS B3H 4J3, Canada

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1998年 / 120卷 / 51期

关键词：

D O I：

10.1021/ja982892x

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：13543 / 13544

页数：2

共 30 条

[1] Direct observation of ultrafast decarboxylation of acyloxy radicals via photoinduced electron transfer in carboxylate ion pairs [J].

Bockman, TM ;

Hubig, SM ;

Kochi, JK .

JOURNAL OF ORGANIC CHEMISTRY, 1997, 62 (07) :2210-2221

[2] Photoinduced electron transfer reactions within zeolites: Detection of radical cations and dimerization of arylalkenes [J].

Brancaleon, L ;

Brousmiche, D ;

Rao, VJ ;

Johnston, LJ ;

Ramamurthy, V .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (20) :4926-4933

[3] ACID ZEOLITES AS ELECTRON-ACCEPTORS - GENERATION OF XANTHYLIUM, DIBENZOTROPYLIUM, AND FLUORENYLIUM CATIONS FROM THEIR CORRESPONDING HYDRIDES THROUGH AN ELECTRON-TRANSFER MECHANISM [J].

CANO, ML ;

CORMA, A ;

FORNES, V ;

GARCIA, H .

JOURNAL OF PHYSICAL CHEMISTRY, 1995, 99 (12) :4241-4246

[4] Intrazeolite photochemistry .12. Ship-in-a-bottle synthesis and control of the photophysical properties of 9-(4-methoxyphenyl)xanthenium ion imprisoned into large-pore zeolites [J].

Cano, ML ;

Cozens, FL ;

Fornes, V ;

Garcia, H ;

Scaiano, JC .

JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (46) :18145-18151

[5] INTRAZEOLITE PHOTOCHEMISTRY .8. INFLUENCE OF THE ZEOLITE PHYSICOCHEMICAL PARAMETERS ON THE LASER FLASH-PHOTOLYSIS OF 1,1-DIPHENYL-2-PROPANONE INCLUDED IN ACID FAUJASITES [J].

COZENS, FL ;

GARCIA, H ;

SCAIANO, JC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (24) :11134-11140

[6] Direct observation of cumyl cations in nonacidic zeolites. Absolute lifetime and reactivity with coabsorbed alcohols [J].

Cozens, FL ;

ONeill, M ;

Schepp, NP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (32) :7583-7584

[7] Alkali metal cation control of oxidation reactions of radicals in zeolites [J].

Cozens, FL ;

Cano, ML ;

García, H ;

Schepp, NP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (23) :5667-5673

[8]

COZENS FL, 1997, J PHYS CHEM-US, V101, P6927

[9] FRAGMENTATION PATHWAYS IN PHOTOLYSIS OF PHENYLACETIC ACID [J].

EPLING, GA ;

LOPES, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (08) :2700-2704

[10] DIFFUSION AND PERCOLATION OF RADICAL PAIRS IN ZEOLITE MEDIA - A PRODUCT ANALYSIS STUDY [J].

GARCIAGARIBAY, MA ;

ZHANG, ZY ;

TURRO, NJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (16) :6212-6218

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