On the activating anionic polymerization of ε-caprolactam in bulk caused by bis carbamyl derivatives

被引：12

作者：

Mateva, R ^{[1
]}

Petrov, P ^{[1
]}

机构：

[1] Univ Chem Technol & Met, Sofia 1156, Bulgaria

来源：

EUROPEAN POLYMER JOURNAL | 1999年 / 35卷 / 02期

关键词：

D O I：

10.1016/S0014-3057(98)00113-X

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The anionic polymerisation of epsilon-caprolactam (epsilon-CL) in the presence of bifunctional N-substituted biscarcarbamyl lactams: hexamethylen-dicarbamyl-dicaprolactam (C-X), and 1-isocyanat 3,3,5 trimethyl-5 methyl cyclohexyl-carbamyl-caprolactam (C-I) was studied. They accelerated the polymerization process and did not cause its poisoning. The kinetics of the polymerization in the presence of both additives was investigated and the activating energy were determined. Their activating effect was compared with the most widely used acylcaprolactam (AL). The different action of C-X C-I were explained by their structural difference. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：325 / 333

页数：9

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