Conversion of a new chiral reagent Δ-[Ru(bpy)2(dmso)Cl] PF6 to Δ-[Ru(bpy)2(dmbpy)]PF6Cl with 96.8% retention of chirality (dmbpy = 4,4′-dimethyl-2,2′-bipyridine)

被引：40

作者：

Hesek, D

Inoue, Y

Everitt, SRL

Ishida, H

Kunieda, M

Drew, MGB

机构：

[1] JST, ERATO, Inoue Photochirogenesis Project, Toyonaka, Osaka 5650085, Japan

[2] Univ Reading, Dept Chem, Reading RG6 6AD, Berks, England

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 05期

关键词：

D O I：

10.1039/a809698h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The new chiral ruthenium bis(bpy) sulfoxide reagent, Delta-cis[Ru(bpy)(2)(dmso)Cl]PF6 (100% ee following HPLC resolution) is used to prepare Delta-[Ru(bpy)(2)(dmbpy)] [PF6]Cl in excellent yield (97%) with almost complete retention of absolute configuration (96.8%), as confirmed by X-ray crystallographic studies on a single enantiomer of [Ru(bpy)(2)(dmbpy)][PF6]Cl (obtained without resolution or chromatographic methods) and by analysis of the optical properties of both the precursor and product.

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页码：403 / 404

页数：2

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