Reactions of the alkyltrihydroaluminate [Li(thf)2{AlH3[C(SiMe3)3]}]2.: Crystal structures of [Li(tmen)2][AlH3{C(SiMe3)3}], [AlBr2-{C(SiMe3)3}]•thf, [AlI2{C(SiMe3)3}]•thf, [Li(thf)2(μ-NHPh)2-{AlH[C(SiMe3)3]}] and {Li(thf)4][Al(NHPh)3{C(SiMe3)3}]

被引：22

作者：

Al-Juaid, SS ^{[1
]}

Eaborn, C ^{[1
]}

Gorrell, IB ^{[1
]}

Hawkes, SA ^{[1
]}

Hitchcock, PB ^{[1
]}

Smith, JD ^{[1
]}

机构：

[1] Univ Sussex, Sch Chem Phys & Environm Sci, Brighton BN1 9QJ, E Sussex, England

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1998年 / 14期

关键词：

D O I：

10.1039/a802145g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The alkyltrihydroaluminate [Li(thf)(2){AlH3[C(SiMe3)(3)]}](2), (thf = tetrahydrofuran) reacted (i) with tetramethylethane-1,2-diamine (tmen) to give [Li(tmen)(2)][AlH3{C(SiMe3)(3)}], which crystallises as solvent-separated ion pairs, (ii) with HCl, HBr or Br-2, or I-2 to give, respectively, the alkylaluminium dihalides [AlX2{C(SiMe3)(3)}].thf, X = Cl, Br or I, which have been characterised spectroscopically and, when X = Br or I, by X-ray diffraction studies; and (iii) with aniline to give [Li(thf)(2)(mu-NHPh)(2)(AlH[C(SiMe3)(3)]}] and [Li(thf)(4)][Al(NHPh)(3){C(SiMe3)(3))], which crystallise as anilide-bridged and solvent-separated ion pairs respectively.

引用

页码：2411 / 2415

页数：5

共 31 条

[1] Complexes of lithium tetrahydroaluminate with N,N,N′,N′-tetra-methylethane-1,2-diamine (tmen).: Crystal structures of [{Li(tmen)-(AlH4)}2] and [Li(tmen)2][AlH4] and the use of the 6Li-{1H} nuclear Overhauser effect to study LiAlH4 and LiBH4 in donor solvents [J].

Andrianarison, MM ;

Avent, AG ;

Ellerby, MC ;

Gorrell, IB ;

Hitchcock, PB ;

Smith, JD ;

Stanley, DR .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1998, (02) :249-253

[2] Preparation and structures of some new pyrrolidinido- and piperidinido-alanes and -aluminates [J].

Andrianarison, MM ;

Ellerby, MC ;

Gorrell, IB ;

Hitchcock, PB ;

Smith, JD ;

Stanley, DR .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (02) :211-217

[3] CRYSTAL-STRUCTURE OF IODODIMETHYL(TRIMETHYLAMINE)-ALUMINUM [J].

ATWOOD, JL ;

MILTON, PA .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1973, 52 (02) :275-281

[4] Organotrialkoxy- and organotrifluoroaluminates: Crystal structures of Li[(Me(3)Si)(3)CAlX(3)]center dot OC4H8 (X=(t)BuO, F) [J].

Avent, AG ;

Chen, WY ;

Eaborn, C ;

Gorrell, IB ;

Hitchcock, PB ;

Smith, JD .

ORGANOMETALLICS, 1996, 15 (21) :4343-4345

[5] DIMETHYLSILOXY-ALUMINIUMDIHALIDE DIMERS - MOLECULAR-STRUCTURES OF [ME2HSIOALX2]2 (X = CL, I) AND [ME3SIOAL(BH4)2]2 [J].

BISSINGER, P ;

MIKULCIK, P ;

RIEDE, J ;

SCHIER, A ;

SCHMIDBAUR, H .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 446 (1-2) :37-43

[6] A NOVEL ALUMINUM CAGE COMPOUND [J].

BOARDMAN, A ;

SMALL, RWH ;

WORRALL, IJ .

INORGANICA CHIMICA ACTA, 1986, 120 (02) :L23-L24

[7] DETERMINATION BY ELECTRON-DIFFRACTION OF THE MOLECULAR-STRUCTURES OF CHLORO-TRIS(TRIMETHYLSILYL)METHANE AND BROMO-TRIS(TRIMETHYLSILYL)METHANE IN THE GAS-PHASE [J].

BRAIN, PT ;

MEHTA, M ;

RANKIN, DWH ;

ROBERTSON, HE ;

EABORN, C ;

SMITH, JD ;

WEBB, AD .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1995, (03) :349-354

[8] SYNTHESIS, STRUCTURE, AND SPECTROSCOPIC CHARACTERIZATION OF UNASSOCIATED MONOAMIDO, DIAMIDO, AND TRIAMIDO DERIVATIVES OF ALUMINUM AND GALLIUM [J].

BROTHERS, PJ ;

WEHMSCHULTE, RJ ;

OLMSTEAD, MM ;

RUHLANDTSENGE, K ;

PARKIN, SR ;

POWER, PP .

ORGANOMETALLICS, 1994, 13 (07) :2792-2799

[9] SOME STERICALLY HINDERED LITHIUM ALKYLBROMO-MAGNESATE AND ALKYLCHLORO-MAGNESATE, CADMATES, AND MANGANATES - CRYSTAL AND MOLECULAR-STRUCTURES OF [LI(THF)2(MU-BR)2MG(C(SIME3)3)(THF)], [LI(THF)4][(CD[C(SIME3)3])3(MU-BR)3(MU-3-BR)].0.5C6H12' [(LI(THF))3(MU-3-BR)3(MU-3-OSIME3)CD(C(SIME3)3)], AND [LI(THF)4][(MN[C(SIME3)3])3-(MU-CL)4(THF)] (THF = TETRAHYDROFURAN)H [J].

BUTTRUS, NH ;

EABORN, C ;

ELKHELI, MNA ;

HITCHCOCK, PB ;

SMITH, JD ;

SULLIVAN, AC ;

TAVAKKOLI, K .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1988, (02) :381-391

[10] Lithium trialkoxo[tris(trimethylsilyl)methyl]aluminates, analogues of intermediates in reductions of carbonyl compounds.: Crystal structures of [Li(thf)2][AlR(OEt)3] and {Li[AlR(OPri)2(OH)]}2, R = C(SiMe3)3 and thf = tetrahydrofuran [J].

Chen, WY ;

Eaborn, C ;

Gorrell, IB ;

Hitchcock, PB ;

Hopman, M ;

Smith, JD .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (24) :4689-4693

← 1 2 3 4 →