Ru(II) and Ru(III) complexes with cyclam and related species

被引：85

作者：

Tfouni, E

Ferreira, KQ

Doro, FG

da Silva, RS

da Rocha, ZN

机构：

[1] Univ Sao Paulo, Fac Filosofia Ciencias & Letras Ribeirao Pret, Dept Quim, BR-14040901 Ribeirao Preto, SP, Brazil

[2] Univ Sao Paulo, Fac Ciencias Farmaceut Ribeirao Preto, BR-14040903 Ribeirao Preto, SP, Brazil

[3] Univ Fed Bahia, Inst Quim, Salvador, BA, Brazil

来源：

COORDINATION CHEMISTRY REVIEWS | 2005年 / 249卷 / 3-4期

基金：

巴西圣保罗研究基金会;

关键词：

cyclam; cyclen; N-substituted cyclam; nitric oxide; ruthenium nitrosyl;

D O I：

10.1016/j.ccr.2004.09.009

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The properties of cyclam, cyclen, and 1-(3-propylammonium) complexes of ruthenium(II/III), [Ru(macrocycle)LL'](n+), and related species are reviewed. L and L' are ligands such as chloro, aqua, hydroxo, nitriles, amides, imides, pyridines, and nitric oxide. These complexes display similarities and differences with related complexes such as Ru(III/II) ammines, with which they are compared and discussed. The factors responsible for the reactivity of the macrocyclic complexes include the macrocycle ring size, the metal oxidation state, and the properties of L and U. Such factors are illustrated with relevant data and recent results concerning the synthesis, structure, electrochemistry, complex reactivity, coordinated ligand reactivity, photochemistry, and electronic, infrared, and NMR spectral data for [Ru(macrocycle)LL'](n+). (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：405 / 418

页数：14

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