Reversible sorption and irreversible binding of naphthalene and alpha-naphthol to soil: Elucidation of processes

被引:77
作者
Burgos, WD
Novak, JT
Berry, DF
机构
[1] VIRGINIA POLYTECH INST & STATE UNIV, DEPT CIVIL ENGN, BLACKSBURG, VA 24061 USA
[2] VIRGINIA POLYTECH INST & STATE UNIV, DEPT CROP & SOIL ENVIRONM SCI, BLACKSBURG, VA 24061 USA
关键词
D O I
10.1021/es950428b
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The sorption and irreversible binding of naphthalene and alpha-naphthol to two sandy soils were evaluated. To determine the extent that biologically-mediated oxidative coupling contributed to the irreversible binding of alpha-naphthol, the presence/absence of O-2 and the presence/absence of biological activity were varied during the sorption period to operationally define biological coupling conditions. After a 2-d sorption period, sorbed material was removed by successive water and solvent extractions, alkali extractions, and combustion. Nonextracted material was defined as the a mount of test compound remaining after solvent extraction (Q(NONEX)) Naphthalene that was not extracted after the 2-d sorption period was caused by mass transfer-limited entrapment within micropores and was used to estimate the fraction of entrapped alpha-naphthol. The principle of superposition was applied to the alpha-naphthol results to determine the contribution of individual irreversible binding processes. Biologically-mediated oxidative coupling accounted for 49.4 +/- 15.0% of Q(NONEX) of alpha-naphthol. Oxidative coupling catalyzed by mineral surfaces accounted for 40.5 +/- 15.8% of Q(NONEX) of alpha-naphthol. Over contact times up to 200 d, nonextracted naphthalene increased from 1.6% to 11.7% of the initially sorbed material, coincident with the biological production of a more polar metabolite.
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页码:1205 / 1211
页数:7
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