共 25 条
Influence of microwave heating on the growth of gadolinium-doped cerium oxide nanorods
被引:95
作者:

Godinho, Mario
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机构:
Univ Fed Sao Carlos, Dept Chem, BR-13565905 Sao Carlos, SP, Brazil Univ Fed Sao Carlos, Dept Chem, BR-13565905 Sao Carlos, SP, Brazil

Ribeiro, Cane
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机构:
EMBRAPA Instrumentacao Agropecuar, BR-13569970 Sao Carlos, SP, Brazil Univ Fed Sao Carlos, Dept Chem, BR-13565905 Sao Carlos, SP, Brazil

Longo, Elson
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机构:
Univ Fed Sao Carlos, Dept Chem, BR-13565905 Sao Carlos, SP, Brazil Univ Fed Sao Carlos, Dept Chem, BR-13565905 Sao Carlos, SP, Brazil

Leite, Edson Roberto
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h-index: 0
机构:
Univ Fed Sao Carlos, Dept Chem, BR-13565905 Sao Carlos, SP, Brazil Univ Fed Sao Carlos, Dept Chem, BR-13565905 Sao Carlos, SP, Brazil
机构:
[1] Univ Fed Sao Carlos, Dept Chem, BR-13565905 Sao Carlos, SP, Brazil
[2] EMBRAPA Instrumentacao Agropecuar, BR-13569970 Sao Carlos, SP, Brazil
关键词:
D O I:
10.1021/cg700872b
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
In this communication, we demonstrate that the use of microwave heating during hydrothermal treatment drastically decreases the treatment time required to obtain gadolinium-doped ceria nanorods and that the oriented attachment is the dominant mechanism responsible for anisotropic growth. In fact, considering oriented attachment (OA) as a statistical mechanism, we postulate that the growth process conducted under microwave heating increases the effective collision rate. A plausible explanation for the increase of the effective collision rate under microwave irradiation is the increase in the collision cross-section of the particle.
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页码:384 / 386
页数:3
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