Multi-functional magnetic, ferroelectric, and fluorescent homochiral lanthanide (Ln)-camphorate compounds built on helical {Ln-O}n inorganic substructures

被引：23

作者：

Song, Yu-mei ^{[1
]}

Huang, Hai-xiao ^{[1
]}

Sun, Gong-ming ^{[1
]}

Liao, Zhen-wei ^{[1
]}

Luo, Ming-biao ^{[1
]}

Liu, Shu-juan ^{[1
]}

Luo, Feng ^{[1
]}

机构：

[1] E China Inst Technol, Coll Biol Chem & Mat Sci, Fuzhou, Jiangxi, Peoples R China

来源：

CRYSTENGCOMM | 2011年 / 13卷 / 22期

基金：

中国博士后科学基金;

关键词：

OPEN-FRAMEWORK MATERIALS; COMPLEXES; CHIRALITY; INDUCTION; CHEMISTRY; TOPOLOGY; STATE; UNITS; ACID;

D O I：

10.1039/c1ce05604b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The design and preparation of homochiral metal-organic coordination polymers is presently a topic of intense focus. Herein, we present a series of isomorphous Ln(III)-camphorate compounds with the P6(5) chiral space group. The overall structural feature is the hex rod-packing architecture, where each helical {Ln-O}(n) inorganic substructure connects to six analogs via chiral D-cam spacers (D-H(2)Cam = D-camphoric acid). Moreover, the Ln-related magnetic, fluorescent and chirality-related ferroelectric merits of these compounds are explored.

引用

页码：6827 / 6830

页数：4

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