Generating palladium nanoclusters inside functional cross-linked polymer frameworks

被引：84

作者：

Corain, B

Kralik, M

机构：

[1] Univ Padua, CNR, Dipartimento Chim Inorgan Met & Analit, I-35131 Padua, Italy

[2] Univ Padua, CNR, Ctr Studio Stabil & Reattiv Composti Coordinaz, I-35131 Padua, Italy

[3] Slovak Univ Technol Bratislava, Dept Organ Technol, Bratislava 81237 1, Slovakia

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2001年 / 173卷 / 1-2期

关键词：

palladium nanoclusters; functional resins; catalysis; nanomorphology; accessibility;

D O I：

10.1016/S1381-1169(01)00147-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The use of functional resins as designable supports for palladium nanoclusters is reviewed. Data are related to the generation of Pd nanoparticles under various conditions and inside gel-type or macroporous frameworks. The combination of different physico-chemical techniques (ISEC, ESR and PGSE NMR) is illustrated as a powerful tool for evaluating nanomorphology and molecular accessibility, mainly of gel-type resins. A few examples of catalytic applications are presented and discussed and prospects for wider utilizations are evaluated. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：99 / 115

页数：17

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