Infrared spectrum and its implications for the electronic structure of the semiconducting iron selenide K0.83Fe1.53Se2

被引:47
作者
Chen, Z. G. [1 ]
Yuan, R. H. [1 ]
Dong, T. [1 ]
Xu, G. [1 ]
Shi, Y. G. [1 ]
Zheng, P. [1 ]
Luo, J. L. [1 ]
Guo, J. G. [1 ]
Chen, X. L. [1 ]
Wang, N. L. [1 ]
机构
[1] Chinese Acad Sci, Beijing Natl Lab Condensed Matter Phys, Inst Phys, Beijing 100190, Peoples R China
关键词
SUPERCONDUCTIVITY; CS;
D O I
10.1103/PhysRevB.83.220507
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We report an infrared spectroscopy study on K0.83Fe1.53Se2, a semiconducting parent compound of the 245 iron selenide superconductors. The major spectral features are found to be distinctly different from all other Fe-based superconducting systems. Our measurement revealed two peculiar spectral structures: a double-peak structure between 4000 and 6000 cm(-1) and abundant phonon modes-much more than expected for a 122 structure. We elaborate that those features could be naturally explained from the blocked antiferromagnetism due to the presence of Fe vacancy ordering as determined by recent neutron-diffraction experiments. The double peaks reflect the coexistence of ferromagnetic and antiferromagnetic couplings between the neighboring Fe sites.
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页数:4
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