Studies of triphenylsilanethiol addition to alkynes: Preparation of vinyl sulfides

被引：11

作者：

Beauchemin, A ^{[1
]}

Gareau, Y ^{[1
]}

机构：

[1] Merck Frosst Ctr Therapeut Res, Pointe Claire, PQ H9R 4P8, Canada

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1998年 / 139卷

关键词：

radical; thiol; vinyl sulfide; silanethiol;

D O I：

10.1080/10426509808035687

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The scope and limitations of triphenylsilanethiol (1) a solid hydrogen sulfide equivalent, were investigated in free radical reactions to terminal alkynes. The triphenylsilylthioenol ether intermediate thus obtained was deprotected with Cs2CO3 in the presence of various electrophiles to yield mixtures of E and Z vinyl sulfides. The ratio of E and Z isomers could be controlled by varying the concentration of the starting alkynes.

引用

页码：187 / 192

页数：6

共 6 条

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