Controlling the aqueous miscibility of ionic liquids: Aqueous biphasic systems of water-miscible ionic liquids and water-structuring salts for recycle, metathesis, and separations

被引:987
作者
Gutowski, KE
Broker, GA
Willauer, HD
Huddleston, JG
Swatloski, RP
Holbrey, JD
Rogers, RD [1 ]
机构
[1] Univ Alabama, Ctr Green Mfg, Tuscaloosa, AL 35487 USA
[2] Univ Alabama, Dept Chem, Tuscaloosa, AL 35487 USA
关键词
D O I
10.1021/ja0351802
中图分类号
O6 [化学];
学科分类号
0703 [化学];
摘要
Hydrophilic ionic liquids can be salted-out and concentrated from aqueous solution upon addition of kosmotropic salts forming aqueous biphasic systems as illustrated by the phase behavior of mixtures of 1-butyl-3-methylimidazolium chloride ([C4mim]Cl) and K3PO4. Copyright © 2003 American Chemical Society.
引用
收藏
页码:6632 / 6633
页数:2
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