Enantiospecific formation of a three-component helical structure by spontaneous self-assembly

被引：11

作者：

Yue, WM ^{[1
]}

Bishop, R ^{[1
]}

Scudder, ML ^{[1
]}

Craig, DC ^{[1
]}

机构：

[1] Univ New S Wales, Sch Chem, Sydney, NSW 2052, Australia

来源：

CHEMISTRY LETTERS | 1998年 / 08期

关键词：

D O I：

10.1246/cl.1998.803

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A toluene solution of the two racemic helical tubulands 1 and 2 yields crystals of the stoichiometric product 1.2(2).toluene through molecular self-assembly involving simultaneous self-resolution of both diols. This composite helical tubulate structure contains parallel tubes with cross-sectional areas of 22.5 Angstrom(2).

引用

页码：803 / 804

页数：2

共 12 条

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