Infinite-dilution binary diffusion coefficients of 2-propanone, 2-butanone, 2-pentanone, and 3-pentanone in CO2 by the Taylor dispersion technique from 308.15 to 328.15 K in the pressure range from 8 to 35 MPa

被引:44
作者
Funazukuri, T
Kong, CY
Kagei, S
机构
[1] Chuo Univ, Inst Sci & Engn, Dept Appl Chem, Bunkyo Ku, Tokyo 1128551, Japan
[2] Yokohama Natl Univ, Dept Informat & Sci, Hodogaya Ku, Yokohama, Kanagawa 2408501, Japan
关键词
binary diffusion coefficient; 2-butanone; carbon dioxide; curve fitting; 2-pentanone; 3-pentanone; 2-propanone; Schmidt number correlation; supercritical; Taylor dispersion method;
D O I
10.1023/A:1006749309979
中图分类号
O414.1 [热力学];
学科分类号
摘要
Infinite-dilution binary diffusion coefficients of 2-propanone. 2-butanone, 2-pentanone, and 3-pentanone in carbon dioxide were measured by the Taylor dispersion method at temperatures from 308.15 to 328.15 K and pressures from 7.60 to 34.57 MPa. The D-12 values were obtained From the response curves by the method of fitting in the time domain. The accuracy in the fitting error was examined for each measurement. The measured D-12 data were found to be well correlated by the Schmidt number correlation, with AAD% = 3.74% for all solutes.
引用
收藏
页码:1279 / 1290
页数:12
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