Iodo(1,10-phenanthroline-N,N′)(triphenylphosphine)copper(I)

被引：23

作者：

Jin, QH ^{[1
]}

Xin, XL

Dong, CJ

Zhu, HJ

机构：

[1] Capital Normal Univ, Dept Chem, Beijing 100037, Peoples R China

[2] Beijing Inst Light Ind, Dept Chem Engn, Beijing 100037, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1998年 / 54卷

关键词：

D O I：

10.1107/S0108270198001991

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the title complex, [CuI(C12H8N2)(C18H15P)], phenanthroline acts as a bidentate ligand coordinating via two N atoms to copper. The coordination polyhedron around the Cu atom is a distorted tetrahedron, with a Cu-P distance of 2.1977 (9) Angstrom, Cu-N distances of 2.111 (3) and 2.071 (3) Angstrom, and a Cu-I distance of 2.6157 (6) Angstrom.

引用

页码：1087 / 1089

页数：3

共 9 条

[1] A LINEAR, MONOMERIC COPPER(I) ACETATE DERIVATIVE, [CU(PHEN)2]2[CU(O2CCH3)2].(O2CCH3)2H - AN EFFECTIVE CATALYST FOR THE DECARBOXYLATION OF CARBOXYLIC-ACIDS [J].

DARENSBOURG, DJ ;

LONGRIDGE, EM ;

ATNIP, EV ;

REIBENSPIES, JH .

INORGANIC CHEMISTRY, 1992, 31 (19) :3951-3955

[2]

FAIT J, 1991, XSCANS USERS MANUAL

[3] STEREOCHEMISTRY OF RIGID CHELATE-METAL COMPLEXES .8. CRYSTAL-STRUCTURES OF ALPHA-(1,10-PHENATHROLINE) AND BETA-(1,10-PHENANTHROLINE)TETRAHYDROBORATO(TRIPHENYLPHOSPHINE)COPPER(I) AND (2,9-DIMETHYL-4,7-DIPHENYL-1,10-PHENANTHROLINE)TETRAHYDROBORATOCOPPER(I) [J].

GREEN, BE ;

KENNARD, CHL ;

SMITH, G ;

ELCOMBE, MM ;

MOORE, FH ;

JAMES, BD ;

WHITE, AH .

INORGANICA CHIMICA ACTA-ARTICLES AND LETTERS, 1984, 83 (03) :177-189

[4]

HEALY PC, 1985, J CHEM SOC DALTON, P2541, DOI 10.1039/dt9850002541

[5]

KRICHHOFF JR, 1985, INORG CHEM, V24, P3928

[6] PHASE ANNEALING IN SHELX-90 - DIRECT METHODS FOR LARGER STRUCTURES [J].

SHELDRICK, GM .

ACTA CRYSTALLOGRAPHICA SECTION A, 1990, 46 :467-473

[7]

SHELDRICK GM, 1993, SHELXL93 PROGRAM REF

[8]

*SIEM, 1991, XEMP EMP ABS CORR PR

[9]

*SIEM, 1994, XP MOL GRAPH PROGR V

← 1 →