Unusual 3D ZnII coordination networks with mixed tetrahedral and square-planar building units: from 2-fold interpenetrating bbf architecture to self-penetrating 86 topological frameworks

被引：50

作者：

Li, Dong-Sheng ^{[1
]}

Ke, Xi-Jun ^{[1
]}

Zhao, Jun ^{[1
]}

Du, Miao ^{[2
]}

Zou, Kun ^{[1
]}

He, Qiu-Fen ^{[1
]}

Li, Cai ^{[1
]}

机构：

[1] China Three Gorges Univ, Coll Mech & Mat Engn, Funct Mat Res Inst, Yichang 443002, Peoples R China

[2] Tianjin Normal Univ, Coll Chem, Tianjin Key Lab Struct & Performance Funct Mol, Tianjin 300387, Peoples R China

来源：

CRYSTENGCOMM | 2011年 / 13卷 / 10期

关键词：

METAL-ORGANIC FRAMEWORKS; RETICULAR CHEMISTRY; MOLECULAR TECTONICS; MAGNETIC-PROPERTIES; HYDROGEN STORAGE; ANION-EXCHANGE; DESIGN; LIGAND; POLYMERS; CRYSTAL;

D O I：

10.1039/c1ce05231d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two unusual 4-connected Zn-II coordination networks have been successfully constructed from tetrahedral ZnII and square-planar 3,3',5,5'-azobenzenetetracarboxylate building units with the aid of comparable N-donor bridging spacers [1,3-bis(imidazol) propane and 1,3-bis(imidazol) butane], which direct the distinct 2-fold interpenetrating (6(4).8(2))(6(6))(2) (bbf) structure with homochiral double-wall helical tubular motifs and the self-penetrating 8(6) network, respectively.

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收藏

页码：3355 / 3359

页数：5

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