Structurally homologous β- and meso-amidinium porphyrins

被引：27

作者：

Yeh, CY ^{[1
]}

Miller, SE ^{[1
]}

Carpenter, SD ^{[1
]}

Nocera, DG ^{[1
]}

机构：

[1] MIT, Dept Chem, Cambridge, MA 02139 USA

来源：

INORGANIC CHEMISTRY | 2001年 / 40卷 / 14期

关键词：

D O I：

10.1021/ic001387+

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A synthetic strategy has been developed to afford porphyrins site-derivatized with the same hydrogen-bond synthon attached directly to the macrocyclic ring. Porphyrin homologues derivatized at the beta and meso positions with an amidinium group form 1:1 supramolecular complexes with benzoate acceptors and show notable differences in their excited-state properties that are dependent on the site of the salt bridge. <Graphics>

引用

页码：3643 / 3646

页数：4

共 32 条

[1] ON PREPARATION OF METALLOPORPHYRINS [J].

ADLER, AD ;

LONGO, FR ;

KAMPAS, F ;

KIM, J .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1970, 32 (07) :2443-&

[2]

Armarego W.L. F., 1996, PURIFICATION LAB CHE, V4th

[3] Internal electron-transfer reactions in cytochrome c oxidase [J].

Brzezinski, P .

BIOCHEMISTRY, 1996, 35 (18) :5611-5615

[4] Xanthene-bridged cofacial bisporphyrins [J].

Chang, CJ ;

Deng, YQ ;

Heyduk, AF ;

Chang, CK ;

Nocera, DG .

INORGANIC CHEMISTRY, 2000, 39 (05) :959-966

[5]

CHANG CJ, ELECT TRANSFER CHEM, P409

[6] SULFITE REDUCTASE STRUCTURE AT 1.6 ANGSTROM - EVOLUTION AND CATALYSIS FOR REDUCTION OF INORGANIC ANIONS [J].

CRANE, BR ;

SIEGEL, LM ;

GETZOFF, ED .

SCIENCE, 1995, 270 (5233) :59-67

[7] Proton-coupled electron transfer [J].

Cukier, RI ;

Nocera, DG .

ANNUAL REVIEW OF PHYSICAL CHEMISTRY, 1998, 49 :337-369

[8] The amidinium-carboxylate salt bridge as a proton-coupled interface to electron transfer pathways [J].

Deng, YQ ;

Roberts, JA ;

Peng, SM ;

Chang, CK ;

Nocera, DG .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (19) :2124-2127

[9]

Deng YQ, 2000, ANGEW CHEM INT EDIT, V39, P1066, DOI 10.1002/(SICI)1521-3773(20000317)39:6<1066::AID-ANIE1066>3.0.CO

[10]

2-G

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