Strong optical limiting of soluble axially substituted gallium and indium phthalocyanines

被引：47

作者：

Chen, Y

Fujitsuka, M

O'Flaherty, SM

Hanack, M

Ito, O

Blau, WJ

机构：

[1] Univ Tubingen, Inst Organ Chem, D-72076 Tubingen, Germany

[2] Tohoku Univ, Inst Multidisciplinary Res Adv Mat, Aoba Ku, Sendai, Miyagi 9808577, Japan

[3] Univ Dublin Trinity Coll, Dept Phys, Dublin 2, Ireland

来源：

ADVANCED MATERIALS | 2003年 / 15卷 / 11期

关键词：

D O I：

10.1002/adma.200304487

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Optical limiting in In- and Ga-phthalocyanines exhibits a range of saturation densities and absorption cross-section ratios. Substitution of the p-trifluoromethyl phenyl group at the central metal in tBu(4)PcGaCl and tBu(4)PcInCl reduces the saturation energy density by a factor of >3. Tailorable optical limiting properties are shown in the Figure, which plots the nonlinear absorption coefficient as a function of intensity for the five compounds studied.

引用

页码：899 / +

页数：5

共 27 条

[1] [Anonymous], PHTHAL PR A
[2] PICOSECOND LASER PHOTOPHYSICS - GROUP-3A PHTHALOCYANINES
BRANNON, JH
MAGDE, D
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (01) : 62 - 65
[3] Chen Y, 1997, J POLYM SCI POL PHYS, V35, P1185, DOI 10.1002/(SICI)1099-0488(199706)35:8<1185::AID-POLB3>3.0.CO
[4] 2-T
[5] Chen Y, 2002, ANGEW CHEM INT EDIT, V41, P3239, DOI 10.1002/1521-3773(20020902)41:17<3239::AID-ANIE3239>3.0.CO
[6] 2-F
[7] Chen Y, 2002, CHEM-EUR J, V8, P4248, DOI 10.1002/1521-3765(20020916)8:18<4248::AID-CHEM4248>3.0.CO
[8] 2-R
[9] Chen Y, 2002, EUR J INORG CHEM, P1032
[10] CHEN Y, 2002, ANGEW CHEM, V114, P3373

← 1 2 3 →