High efficiency polymer solar cells via sequential inkjet-printing of PEDOT:PSS and P3HT:PCBM inks with additives

被引：133

作者：

Eom, Seung Hun ^{[1
,2
]}

Park, Hanok ^{[1
]}

Mujawar, S. H. ^{[1
]}

Yoon, Sung Cheol ^{[3
]}

Kim, Seok-Soon ^{[4
]}

Na, Seok-In ^{[3
,5
]}

Kang, Seok-Ju ^{[6
]}

Khim, Dongyoon ^{[6
]}

Kim, Dong-Yu ^{[6
]}

Lee, Soo-Hyoung ^{[1
]}

机构：

[1] Chonbuk Natl Univ, Sch Semicond & Chem Engn, Jeonju 561756, South Korea

[2] Korea Elect Technol Inst, Korea Printed Elect Ctr, Jeonju 561844, South Korea

[3] Korea Res Inst Chem Technol, Adv Mat Div, Taejon 305600, South Korea

[4] Kunsan Natl Univ, Dept Nano & Chem Engn, Kunsan 751701, South Korea

[5] KIST, Wanju Gun 565902, Jeollabuk Do, South Korea

[6] GIST, Dept Mat Sci & Engn, Heeger Ctr Adv Mat, Kwangju 500712, South Korea

来源：

ORGANIC ELECTRONICS | 2010年 / 11卷 / 09期

关键词：

Polymer solar cell; Inkjet-printing; P3HT:PCBM; Active layer; Ink additives; PERFORMANCE; POLYTHIOPHENE; MORPHOLOGY; NETWORK; FILMS;

D O I：

10.1016/j.orgel.2010.06.007

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Highly efficient and cost-effective polymer solar cells (PSCs) based poly(3-hexylthiophene) (P3HT) and 1-(3-methoxycarbonyl)-propyl-1-phenyl-(6,6)C61 (PCBM) have been fabricated by inkjet-printing with various additives. All solution-processed layers in the solar cells-a poly(3,4-ethylenedioxythiophene): poly(styrenesulfonate) (PEDOT:PSS) layer and a photoactive layer based on P3HT and PCBM with additives-were inkjet-printed. The device performance is strongly influenced by the addition of high boiling point additives in the photoactive ink with chlorobenzene (CB) solvent. The morphology, optoelectronic properties, and overall solar cell performance of the devices were dramatically affected by additives, such as 1,8 octanedithiol (ODT), o-dichlorobenzene (ODCB) and chloronaphthalene (Cl-naph). A device fabricated from ink formulated with ODT exhibited the best overall performance with power conversion efficiency (PCE) of 3.71%. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：1516 / 1522

页数：7

共 40 条

[1] Polymer based organic solar cells using ink-jet printed active layers [J].

Aernouts, T. ;

Aleksandrov, T. ;

Girotto, C. ;

Genoe, J. ;

Poortmans, J. .

APPLIED PHYSICS LETTERS, 2008, 92 (03)

[2] Solvent mixtures for improving device efficiency of polymer photovoltaic devices [J].

Chen, Fang-Chung ;

Tseng, Hsin-Chen ;

Ko, Chu-Jung .

APPLIED PHYSICS LETTERS, 2008, 92 (10)

[3] Influence of nanomorphology on the photovoltaic action of polymer-fullerene composites [J].

Chirvase, D ;

Parisi, J ;

Hummelen, JC ;

Dyakonov, V .

NANOTECHNOLOGY, 2004, 15 (09) :1317-1323

[4] Characterization of organic solar cells: the importance of device layout [J].

Cravino, Antonio ;

Schilinsky, Pavel ;

Brabec, Christoph J. .

ADVANCED FUNCTIONAL MATERIALS, 2007, 17 (18) :3906-3910

[5] Preparation and characterization of nano-scale ZnO as a buffer layer for inkjet printing of silver cathode in polymer solar cells [J].

Eom, Seung Hun ;

Senthilarasu, S. ;

Uthirakumar, Periyayya ;

Hong, Chang-Hee ;

Lee, Youn-Sik ;

Lim, Jongsun ;

Yoon, Sung Cheol ;

Lee, Changjin ;

Lee, Soo-Hyoung .

SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2008, 92 (05) :564-570

[6] Polymer solar cells based on inkjet-printed PEDOT:PSS layer [J].

Eom, Seung Hun ;

Senthilarasu, S. ;

Uthirakumar, Periyayya ;

Yoon, Sung Cheol ;

Lim, Jongsun ;

Lee, Changjin ;

Lim, Hyun Seok ;

Lee, J. ;

Lee, Soo-Hyoung .

ORGANIC ELECTRONICS, 2009, 10 (03) :536-542

[7] Correlation between structural and optical properties of composite polymer/fullerene films for organic solar cells [J].

Erb, T ;

Zhokhavets, U ;

Gobsch, G ;

Raleva, S ;

Stühn, B ;

Schilinsky, P ;

Waldauf, C ;

Brabec, CJ .

ADVANCED FUNCTIONAL MATERIALS, 2005, 15 (07) :1193-1196

[8] Laminated fabrication of polymeric photovoltaic diodes [J].

Granström, M ;

Petritsch, K ;

Arias, AC ;

Lux, A ;

Andersson, MR ;

Friend, RH .

NATURE, 1998, 395 (6699) :257-260

[9] Effects of film treatment on the performance of poly(3-hexylthiophene)/soluble fullerene-based organic solar cells [J].

Guo, Tzung-Fang ;

Wen, Ten-Chin ;

Pakhomov, Georgi L'vovich ;

Chin, Xing-Guo ;

Liou, Siou-Hong ;

Yeh, Pei-Hong ;

Yang, Cheng-Hsien .

THIN SOLID FILMS, 2008, 516 (10) :3138-3142

[10] EFFICIENT PHOTODIODES FROM INTERPENETRATING POLYMER NETWORKS [J].

HALLS, JJM ;

WALSH, CA ;

GREENHAM, NC ;

MARSEGLIA, EA ;

FRIEND, RH ;

MORATTI, SC ;

HOLMES, AB .

NATURE, 1995, 376 (6540) :498-500

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