A chemical-responsive supramolecular hydrogel from modified cycloclextrins

被引：152

作者：

Deng, Wei ^{[1
]}

Yamaguchi, Hiroyasu ^{[1
]}

Takashima, Yoshinori ^{[1
]}

Harada, Akira ^{[1
]}

机构：

[1] Osaka Univ, Grad Sch Sci, Dept Macromol Sci, Toyonaka, Osaka 5600043, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 27期

关键词：

cyclodextrins; host-guest systems; hydrogels; self-assembly; supramolecular chemistry;

D O I：

10.1002/anie.200701272

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) No backbone required: A supramolecular hydrogel has been synthesized from a guest-modified cyclodextrin (CD) without a polymer backbone. The β-CD forms supramolecular fibrils through host-guest interactions, and then hydrogen bonds between the CDs cross-link the fibrils to give a hydrogel. Gel-to-sol transitions can be effected by adding a competitive guest or a denaturing reagent (see example). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：5144 / 5147

页数：4

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