Electrical analysis of Li/SOCl2 cell connected with electrochemical capacitor

被引:13
作者
Chung, KI [1 ]
Lee, JS [1 ]
Ko, YO [1 ]
机构
[1] Vitzrocell Co Ltd, R&D Ctr, Chungnam 340861, South Korea
关键词
voltage delay; parallel connection; electrochemical capacitor; impedance; lithium battery;
D O I
10.1016/j.jpowsour.2004.08.043
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A Li/SOCl2 bobbin-type cell, connected in parallel with an electrochemical capacitor, is investigated in order to overcome the voltage delay problem at high-rate discharge. In spite of the high internal resistance of the Li/SOCl2 cell due to the passivation, the voltage delay is suppressed. Impedance measurements, in which the cell is separated from the capacitor, explain the suppression process clearly. The electrochemical capacitor operates as a high-current buffer and voltage-delay suppressor for the Li/SOCl2 bobbin-type cell. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:376 / 380
页数:5
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