Compounds of triphenylstibine and platinum:: synthesis, properties and reactivity

被引：2

作者：

Barbiéri, RS ^{[1
]}

Bellato, CR

Massabni, AC

机构：

[1] Univ Vale do Rio Verde, UNINCOR, BR-36570000 Tres Coracoes, MG, Brazil

[2] Fac Minas, FAMINAS, BR-36880000 Muriae, MG, Brazil

[3] Univ Fed Vicosa, BR-36570000 Vicosa, MG, Brazil

[4] Univ Estadual Paulista Julio de Mesquita Filho, UNESP, BR-14800900 Araraquara, SP, Brazil

来源：

TRANSITION METAL CHEMISTRY | 2005年 / 30卷 / 02期

关键词：

D O I：

10.1007/s11243-004-3668-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactivity of [Pt(SbPh3)(3)], a compound of zerovalent platinum, exceptionally stable in air, is described. The compounds [{Pt(SbPh3)(3)}(2)N-2], containing bridging dinitrogen, [{Pt(SbPh3)(3)}(2)C-2], with an ethynediyl group also bridging, and [Pt(CO)(2)(SbPh3)(2)], were all obtained under ordinary pressure of nitrogen, acetylene or carbon monoxide, respectively, and are also described. Among the products of the reactions, the dimer [PtBr3(SbPh3)(2)](2) and the mixed complexes [PtL2(SbPh3)(2)] (L = PPh3, AsPh3) were also obtained. Some of these complexes are luminescent when excited by u.v. radiation.

引用

页码：217 / 220

页数：4

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