Estimation of heat of vaporization of pure liquid at its normal boiling temperature

被引:22
作者
Liu, ZY [1 ]
机构
[1] Hebei Univ Technol, Dept Chem Engn, Tianjin 300130, Peoples R China
关键词
heat of vaporization; thermodynamic properties;
D O I
10.1080/00986440108912849
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
A new method is proposed to estimate the heat or vaporization of pure liquid at its normal boiling temperature. The properties required include the boiling temperature, critical temperature and critical pressure. For monohydric alcohol and monohydric organic acid, an adjusting-boiling-temperature strategy is proposed to reduce the calculation errors. The method is tested for 160 substances including many groups of compounds. The results show that the proposed method is better than the literature methods, especially for monohydric alcohol and monohydric acid.
引用
收藏
页码:221 / 228
页数:8
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