Access to planar chirality through cycloplatination of ((dimethylamino)methyl)ferrocene by cis-[PtCl2(SOMeAr)2] (Ar = phenyl, p-tolyl)

被引：33

作者：

Ryabov, AD ^{[1
]}

Panyashkina, IM

Polyakov, VA

Howard, JAK

Kuz'mina, LG

Datt, MS

Sacht, C

机构：

[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119899, Russia

[2] GV Plekhanov Russian Econ Acad, Div Chem, Moscow 113054, Russia

[3] DI Mendeleev Moscow Acad Chem Technol, Moscow 125820, Russia

[4] Univ Durham, Dept Chem, Durham DH1 31E, England

[5] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 117907, Russia

[6] Rhodes Univ, Dept Chem, ZA-6140 Grahamstown, South Africa

来源：

ORGANOMETALLICS | 1998年 / 17卷 / 16期

关键词：

D O I：

10.1021/om971076f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A reaction between ((dimethylamino)methyl)ferrocene and the enantiomerically pure complex cis-[PtCl2(S-SOMeC6H4Me-p)(2)] affords the two easily separable cycloplatinated SsRp and SsSp diastereoisomers 4 and 5, respectively. The absolute configuration of 4 was established by an X-ray study. Diastereomers 4 and 5 react with PPh3 to give enantiomers with the planar chirality only.

引用

页码：3615 / 3618

页数：4

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