The conversion of methane with silica-supported platinum catalysts: the effect of catalyst preparation method and platinum particle size

被引：14

作者：

Eswaramoorthy, M ^{[1
]}

Niwa, S ^{[1
]}

Toba, M ^{[1
]}

Shimada, H ^{[1
]}

Raj, A ^{[1
]}

Mizukami, F ^{[1
]}

机构：

[1] Natl Inst Mat & Chem Res, 1-1 Higashi, Ibaraki 3058565, Japan

来源：

CATALYSIS LETTERS | 2001年 / 71卷 / 1-2期

关键词：

methane; non-oxidative dehydrogenation; mesoporous; Pt-silica;

D O I：

10.1023/A:1016652207819

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The particle size distribution of platinum in silica prepared by the complexing agent-assisted sol-gel method and impregnation method and also in MCM-41 has been compared and its influence on the product distribution in the non-oxidative dehydrogenation of methane has been investigated. The sol-gel method gives a narrow range of platinum particle size distribution compared to the impregnation method. It was found that as the particle size increases, the selectivity for the higher hydrocarbons increases though the yield decreases.

引用

页码：55 / 61

页数：7

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