Photoinduced charge separation through a negatively charged bridge

被引：17

作者：

Fanni, S

Keyes, TE

Campagna, S

Vos, JG ^{[1
]}

机构：

[1] Dublin City Univ, Sch Chem Sci, Dublin 9, Ireland

[2] Univ Messina, Dipartimento Chim Inorgan Analit & Struttura Mol, I-98166 Messina, Italy

来源：

INORGANIC CHEMISTRY | 1998年 / 37卷 / 22期

关键词：

D O I：

10.1021/ic980347r

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel ruthenium polypyridyl dyad has been prepared. In this compound the electron donor phenothiazine is covalently bound to the Ru(bpy)2 center (bpy = 2,2'-bipyridyl) through a negatively charged 1,2,4-triazolate ring. In a flash-quench experiment employing methyl viologen as acceptor, electron transfer across the triazolate bridge is observed.

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页码：5933 / +

页数：4

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