Palladium catalyzed arylation for the synthesis of polyarenes

被引：106

作者：

Pascual, Sergio

de Mendoza, Paula

Echavarren, Antonio M.

机构：

[1] Inst Chem Res Catalonia ICIQ, Tarragona 43007, Spain

[2] Univ Autonoma Madrid, Dept Quim Organ, E-28049 Madrid, Spain

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2007年 / 5卷 / 17期

关键词：

D O I：

10.1039/b707940k

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We present the current understanding on the mechanism of palladium-catalyzed arylation, which involves a proton abstraction by the base. In addition, we present selected examples of the application of this reaction for the synthesis of large polyarenes to highlight the variety of catalysts and reaction conditions that are currently used.

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页码：2727 / 2734

页数：8

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