A novel zirconium polyoxometalate complex that contains both a coordinated saturated anion, [PMo12O40]3-, and a coordinated unsaturated anion, [PMo11O39]7-

被引：42

作者：

Gaunt, AJ

May, I

Collison, D

Fox, OD

机构：

[1] Univ Manchester, Dept Chem, Ctr Radiochem Res, Manchester M13 9PL, Lancs, England

[2] BNFL, Res & Technol, Seascale CA20 1PG, Cumbria, England

来源：

INORGANIC CHEMISTRY | 2003年 / 42卷 / 17期

关键词：

D O I：

10.1021/ic034273h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The novel 8-coordinate zirconium compound (NH4)(6)[Zr(PMo12O40)(PMo11O39)].26H(2)O (1) has been synthesized and characterized by single-crystal X-ray diffraction, elemental analysis, and vibrational and P-31 NMR spectroscopy. It is the first example of a metal complex containing both parent, [PMo12O40](3-), and monovacant lacunary, [PMo11O39](7-), anions. Furthermore, this is the first crystallographic determination of the [PMo11O39](7-) anion.

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页码：5049 / 5051

页数：3

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