Studies of ansa-bis(cyclopentadienyl)tungsten derivatives

被引:40
作者
Conway, SLJ [1 ]
Dijkstra, T [1 ]
Doerrer, LH [1 ]
Green, JC [1 ]
Green, MLH [1 ]
Stephens, AHH [1 ]
机构
[1] Univ Oxford, Inorgan Chem Lab, Oxford OX1 3QR, England
来源
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1998年 / 16期
关键词
D O I
10.1039/a803076f
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The new compounds [W{(eta-C5H4)X(eta-C5H4)}Cl-2] 1, [W{(eta-C5H4)X(eta-C5H4)}Me-2] 2, [W{(eta-C5H4)SiMe2-(eta-C5H4)}(SPh)(2)] 3, [W{(eta-C5H4)X(eta-C5H4)}H(Cl)] 4, [W{(eta-C5H4)X(eta-C5H4)}H-2] 5 and [W{(eta-C5H4)X(eta-C5H4)}H-3]Y-+(-) 6, where X = SiMe2, SiEt2 or CMe2CMe2, and Y = BF4 or Cl, have been prepared. The crystal structures of [W{(eta-C5H4)X(eta-C5H4)}Me-2] (X = SiMe2 or CMe2CMe2) have been determined.
引用
收藏
页码:2689 / 2695
页数:7
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