Discrete yttrium(III) complexes as lactide polymerization catalysts

被引：139

作者：

Chamberlain, BM ^{[1
]}

Sun, YP ^{[1
]}

Hagadorn, JR ^{[1
]}

Hemmesch, EW ^{[1
]}

Young, VG ^{[1
]}

Pink, R ^{[1
]}

Hillmyer, MA ^{[1
]}

Tolman, WB ^{[1
]}

机构：

[1] Univ Minnesota, Dept Chem, Minneapolis, MN 55455 USA

来源：

MACROMOLECULES | 1999年 / 32卷 / 07期

关键词：

D O I：

10.1021/ma990005k

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A set of novel yttrium complexes that display unprecedented coordination geometries for the ligands S-H3LMe, R-H3LiPr, and H3LMe is developed. These complexes are promising catalysts for the ring-opening polymerization of lactide. The demonstration of readily manipulated ligand effects on polymerization reactivity in these discrete, well-characterized complexes represents an important step in the development of highly selective lanthanide catalysts for the controlled synthesis of polylactide acid and other polyesters.

引用

页码：2400 / 2402

页数：3

共 26 条

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