Infrared chalcogen glasses: chemical polishing and fibre remote spectroscopy

被引:30
作者
Le Coq, D [1 ]
Michel, K [1 ]
Fonteneau, G [1 ]
Hocde, S [1 ]
Boussard-Pledel, C [1 ]
Lucas, J [1 ]
机构
[1] Univ Rennes 1, UMR CNRS 6512, Lab Verres & Ceram, F-35042 Rennes, France
来源
INTERNATIONAL JOURNAL OF INORGANIC MATERIALS | 2001年 / 3卷 / 03期
关键词
D O I
10.1016/S1466-6049(01)00007-1
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Inorganic vitreous polymers based on the combination of the chalcogen elements Se, Te and As are investigated on account of their unique transparency in the infrared spectral domain leading to applications in night-vision systems as well as in IR remote fibre spectroscopy. An original procedure of chemical polishing using a congruent dissolution process of the glass is developed in order to produce outstanding optical quality surfaces. The same methodology is applied to produce tapered chalcogen glass fibres used as IR evanescent wave chemical sensors. In reducing the fibre diameter by chemical etching, a significant improvement in the sensitivity of the optical sensor operating in the 2 to 12 mum spectral region is observed. This original optical configuration is applied to some in situ chemical or biological analysis. (C) 2001 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:233 / 239
页数:7
相关论文
共 4 条
[1]   Infrared glass fibers for evanescent wave spectroscopy [J].
Boussard-Plédel, C ;
Hocdé, S ;
Fonteneau, G ;
Ma, HL ;
Zhang, XH ;
Le Foulgoc, K ;
Lucas, J ;
Perio, B ;
Hamelin, J .
SPECIALTY FIBER OPTICS FOR MEDICAL APPLICATIONS, PROCEEDINGS OF, 1999, 3596 :91-98
[2]   QUANTITATIVE-EVALUATION OF CHALCOGENIDE GLASS-FIBER EVANESCENT-WAVE SPECTROSCOPY [J].
KATZ, M ;
KATZIR, A ;
SCHNITZER, I ;
BORNSTEIN, A .
APPLIED OPTICS, 1994, 33 (25) :5888-5894
[3]   Etched chalcogenide fibers for near-field infrared scanning microscopy [J].
Unger, MA ;
Kossakovski, DA ;
Kongovi, R ;
Beauchamp, JL ;
Baldeschwieler, JD ;
Palanker, DV .
REVIEW OF SCIENTIFIC INSTRUMENTS, 1998, 69 (08) :2988-2993
[4]   LOW-LOSS OPTICAL FIBERS OF THE TELLURIUM HALIDE-BASED GLASSES, THE TEX GLASSES [J].
ZHANG, XH ;
MA, HL ;
BLANCHETIERE, C ;
LUCAS, J .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1993, 161 :327-330