A new rhodamine-based fluorescent chemosensor for transition metal cations synthesized by one-step facile condensation

被引:138
作者
Zhang, Xuan
Shiraishi, Yasuhiro [1 ]
Hirai, Takayuki
机构
[1] Osaka Univ, Grad Sch Engn Sci, Res Ctr Solar Energy Chem, Toyonaka, Osaka 5608531, Japan
[2] Osaka Univ, Grad Sch Engn Sci, Div Chem Engn, Toyonaka, Osaka 5608531, Japan
关键词
D O I
10.1016/j.tetlet.2007.05.171
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A new rhodamine-based fluorescent chemosensor (1) for transition metal cations was synthesized by one-step facile condensation of rhodamine B and 2-aminopyridine. Without metal cations, I is colorless and nonfluorescent, whereas addition of metal cations (Fe3+, Hg2+, Pb2+, and Fe2+) leads to an obvious color change to pink and an appearance of orange fluorescence. (c) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码:5455 / 5459
页数:5
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