Determination of cyanide in waste waters using a quartz crystal microbalance

被引:9
作者
Gomes, MTSR [1 ]
Silva, AAF [1 ]
Duarte, AC [1 ]
Oliveira, JABP [1 ]
机构
[1] Univ Aveiro, Dept Chem, P-3810 Aveiro, Portugal
关键词
quartz crystal microbalance; piezoelectric crystals; cyanide;
D O I
10.1016/S0925-4005(98)00075-6
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A method based on a quartz crystal microbalance (QCM) was used for the first time to analyse cyanide in real samples. The method was applied to the analysis of waste waters from an electroplating industry. The analysis of replicates of five different samples ranging from 0.931 to 853 mg l(-1) showed relative standard deviations between 1.7% and 9.3%. There was no evidence of systematic differences between the two sets of results obtained by the QCM method or by the ASTM method. However, the QCM method was faster and needed a sample volume 100 times smaller than the ASTM method. (C) 1998 Elsevier Science S.A. All rights reserved.
引用
收藏
页码:383 / 386
页数:4
相关论文
共 3 条
[1]  
*ASTM, 1985, 1985 ANN BOOK ASTM S, P112
[2]   Optimisation of the experimental conditions of a new method, based on a quartz crystal microbalance, for the determination of cyanide [J].
Gomes, MTSR ;
Silva, AAF ;
Duarte, AC ;
Oliveira, JABP .
ANALYST, 1997, 122 (10) :1139-1141
[3]   MERCURY DISPLACEMENT DETECTION FOR THE DETERMINATION OF PICOGRAM AMOUNTS OF SULFITE ION OR SULFUR-DIOXIDE BY ATOMIC SPECTROMETRY [J].
MARSHALL, G ;
MIDGLEY, D .
ANALYTICAL CHEMISTRY, 1981, 53 (12) :1760-1765