Mid-infrared fiber-optics reflectance spectroscopy: A noninvasive technique for remote analysis of painted layers. Part I: Technical setup

被引:41
作者
Fabbri, M [1 ]
Picollo, M [1 ]
Porcinai, S [1 ]
Bacci, M [1 ]
机构
[1] CNR, IROE Nello Carrara, I-50127 Florence, Italy
关键词
fiber-optics FT-IR spectroscopy; reflectance spectroscopy; noninvasive analysis; painted layers;
D O I
10.1366/0003702011952172
中图分类号
TH7 [仪器、仪表];
学科分类号
0804 ; 080401 ; 081102 ;
摘要
Mid-infrared chalcogenide fiber optics coupled with Fourier transform infrared (FT-LR) benches has made it possible to perform noninvasive reflectance measurements of lavers of paint. The technique has potential applications for noninvasive anal, sis of works of art. These measurements can present large distortions in the spectrum both in band shape and absorption frequency, which may depend on the band strength, on the concentration of the sample, or oil the optical la out of the measuring system, Therefore, it is difficult to compare reflectance spectra with those collected in the transmission mode and, consequently, with the available databases, The work deals with an overall survey of the limits and problems involved in the utilization of this analytical technique, an estimate of the reproducibility of the measurements, and the development of a correct measurement procedure.
引用
收藏
页码:420 / 427
页数:8
相关论文
共 20 条
[1]   FIBER OPTICS APPLICATIONS TO WORKS-OF-ART [J].
BACCI, M .
SENSORS AND ACTUATORS B-CHEMICAL, 1995, 29 (1-3) :190-196
[2]   QUANTITATIVE DIFFUSE REFLECTANCE AND TRANSMITTANCE INFRARED-SPECTROSCOPY OF NONDILUTED POWDERS [J].
BOROUMAND, F ;
MOSER, JE ;
VANDENBERGH, H .
APPLIED SPECTROSCOPY, 1992, 46 (12) :1874-1886
[3]   ANGULAR-DEPENDENCE OF DIFFUSE REFLECTANCE INFRARED-SPECTRA .3. LINEARITY OF KUBELKA-MUNK PLOTS [J].
BRIMMER, PJ ;
GRIFFITHS, PR .
APPLIED SPECTROSCOPY, 1988, 42 (02) :242-247
[4]   ANGULAR-DEPENDENCE OF DIFFUSE REFLECTANCE INFRARED-SPECTRA .1. FT-IR SPECTROGONIOPHOTOMETER [J].
BRIMMER, PJ ;
GRIFFITHS, PR ;
HARRICK, NJ .
APPLIED SPECTROSCOPY, 1986, 40 (02) :258-265
[5]   ANGULAR-DEPENDENCE OF DIFFUSE REFLECTANCE INFRARED-SPECTRA .2. EFFECT OF POLARIZATION [J].
BRIMMER, PJ ;
GRIFFITHS, PR .
APPLIED SPECTROSCOPY, 1987, 41 (05) :791-797
[6]   EFFECT OF SCATTERING COEFFICIENT ON DIFFUSE REFLECTANCE INFRARED-SPECTRA [J].
FRASER, DJJ ;
GRIFFITHS, PR .
APPLIED SPECTROSCOPY, 1990, 44 (02) :193-199
[7]   ANOMALOUS DISPERSION EFFECTS IN DIFFUSE REFLECTANCE INFRARED FOURIER-TRANSFORM SPECTROSCOPY - A STUDY OF OPTICAL GEOMETRIES [J].
HEMBREE, DM ;
SMYRL, HR .
APPLIED SPECTROSCOPY, 1989, 43 (02) :267-274
[8]  
hite W.B, 1974, INFRARED SPECTRA MIN, P227
[9]  
ISHIGAME M, 1971, PHYS REV B, V12, P4388
[10]  
Korte E.H, 1995, INFRARED RAMAN SPECT, P572