X-ray studies of polymer/gold nanocomposites

被引:46
作者
Lin, BH
Morkved, TL
Meron, M
Huang, ZQ
Viccaro, PJ
Jaeger, HM
Williams, SM
Schlossman, ML
机构
[1] James Franck Institute, Ctr. for Advanced Radiation Sources, University of Chicago, Chicago
[2] James Franck Institute, Department of Physics, University of Chicago, Chicago
[3] Department of Physics, University of Illinois (M/C 273), Chicago
[4] Department of Chemistry, University of Minnesota, Minneapolis
关键词
D O I
10.1063/1.369658
中图分类号
O59 [应用物理学];
学科分类号
摘要
We demonstrate that x-ray reflection standing wave fluorescence spectroscopy is a highly sensitive technique for the determination of the distribution of metal nanoparticles inside polymer thin films. We investigate both the depth profile and the in-plane spatial correlation of gold nanoparticles in an asymmetric polystyrene-b-poly(2-vinylpyridine) block copolymer film. These copolymer films self-assemble into alternating, nanometer-sized domains that are, upon annealing, selectively decorated by thermally evaporated metal nanoparticles to form metal/polymer composites. (C) 1999 American Institute of Physics. [S0021-8979(99)02706-1].
引用
收藏
页码:3180 / 3184
页数:5
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