Modulation of iron reduction potential by deprotonation at a remote site

被引:72
作者
Carina, RF
Verzegnassi, L
Bernardinelli, G
Williams, AF
机构
[1] Univ Geneva, Dept Inorgan Analyt & Appl Chem, CH-1211 Geneva 4, Switzerland
[2] Univ Geneva, Lab Xray Crystallog, CH-1211 Geneva, Switzerland
关键词
D O I
10.1039/a807321j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Remote site deprotonation of a coordinated imidazole ligand switches the reduction potential of coordinated iron over a narrow pH range from +0.920 to -0.460 V.
引用
收藏
页码:2681 / 2682
页数:2
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