Determination of interfacial tension from crystallization and dissolution data: a comparison with other methods

被引:170
作者
Wu, WJ [1 ]
Nancollas, GH [1 ]
机构
[1] SUNY Buffalo, Dept Chem, Buffalo, NY 14260 USA
基金
美国国家卫生研究院;
关键词
interfacial tension; solubility; crystallization; dissolution; contact angle; thin layer wicking;
D O I
10.1016/S0001-8686(98)00072-4
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Methods for the determination of interfacial tension between a solid and a liquid are reviewed including solubility/particle size, crystallization and dissolution kinetics. The use of solubility as a function of particle size, originally put forward by Ostwald and later corrected by Freundlich, may be unjustified for determining interfacial tension at solid-liquid interfaces. The interfacial tension values between solutions and sparingly soluble minerals such as hydroxyapatite, fluorapatite, brushite, octacalcium phosphate, calcium oxalate monohydrate, barium sulfate, calcium sulfate, calcite, and divalent metal fluorides are discussed. A comparison of these results is made with contact angle or wetting measurements. The interfacial tension values obtained from constant composition reaction kinetics are of the same order of magnitude as those determined using a contact angle method involving thin layer wicking techniques. (C) 1999 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:229 / 279
页数:51
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