New phytoecdysteroids from roots of Ajuga reptans varieties.

被引:28
作者
Calcagno, MP
Camps, F
Coll, J
Mele, E
SanchezBaeza, F
机构
[1] CSIC,CID,DEPT BIOL ORGAN CHEM,E-08034 BARCELONA,SPAIN
[2] IRTA,DEPT PLANT GENET,E-08348 BARCELONA,SPAIN
[3] UNIV LOS ANDES,MERIDA,VENEZUELA
关键词
D O I
10.1016/0040-4020(96)00536-4
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Reptansterone (8), anew C-29 phytoecdysteroid with a delta-lactone in the side chain, was isolated from roots of a green variety of Ajuga reptans. Likewise, other unprecedented members of this polyhydroxysteroid family namely 28-epi-sengosterone (9), 5,29-dihydroxycapitasterone (10) 2- and 3-dehydroajugalactone (11 and 12) were isolated from A. reptans var. atropurpurea. The structures of all these new compounds were inferred fi-om the corresponding H-1 and C-13-NMR homo- and heterocorrelations and IR and HPLC-MS(TSP) spectral data Copyright (C) 1996 Elsevier Science Ltd
引用
收藏
页码:10137 / 10146
页数:10
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