Hydrogen peroxide improving crystallinity of TiO2 nanoparticle in layer compound

被引:21
作者
Ooka, C
Yoshida, H
Takeuchi, S
Maekawa, M
Yamada, Z
Hattori, T
机构
[1] Nagoya Municipal Ind Res Inst, Atsuta Ku, Nagoya, Aichi 4560058, Japan
[2] Nagoya Univ, Res Ctr Adv Waste & Emiss Management, Chikusa Ku, Nagoya, Aichi 4648603, Japan
[3] Sinto V Cerax Ltd, Toyokawa 4428505, Japan
[4] Nagoya Univ, Grad Sch Engn, Dept Appl Chem, Chikusa Ku, Nagoya, Aichi 4648603, Japan
关键词
TiO2 pillared clay; photocatalyst; hydrogen peroxide; crystallinity;
D O I
10.1016/j.catcom.2003.11.009
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
TiO2 nanoparticle in the pillared montmorillonite was crystallized to become anatase phase by treatment with aqueous hydrogen peroxide at room temperature without losing both the porous structure and the hydrophobicity of the pillared clay. The resulting pillared clay showed higher photocatalytic activity than the untreated pillared clay in degradation of di-n-butyl phthalate in water. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码:49 / 54
页数:6
相关论文
共 23 条
[1]   PHOTOLUMINESCENCE AND PHOTOCATALYTIC ACTIVITY OF HIGHLY DISPERSED TITANIUM-OXIDE ANCHORED ONTO POROUS VYCOR GLASS [J].
ANPO, M ;
AIKAWA, N ;
KUBOKAWA, Y ;
CHE, M ;
LOUIS, C ;
GIAMELLO, E .
JOURNAL OF PHYSICAL CHEMISTRY, 1985, 89 (23) :5017-5021
[2]   INFLUENCE OF HYDROGEN-PEROXIDE ON THE KINETICS OF PHENOL PHOTODEGRADATION IN AQUEOUS TITANIUM-DIOXIDE DISPERSION [J].
AUGULIARO, V ;
DAVI, E ;
PALMISANO, L ;
SCHIAVELLO, M ;
SCLAFANI, A .
APPLIED CATALYSIS, 1990, 65 (01) :101-116
[3]   SYNTHESIS AND CHARACTERIZATION OF TITANIUM PILLARED CLAYS - INFLUENCE OF THE TEMPERATURE OF PREPARATION [J].
BERNIER, A ;
ADMAIAI, LF ;
GRANGE, P .
APPLIED CATALYSIS, 1991, 77 (02) :269-281
[4]   SYNTHESIS AND CHARACTERIZATION OF TITANIUM-PILLARED MONTMORILLONITES [J].
BOUDALI, LK ;
GHORBEL, A ;
TICHIT, D ;
CHICHE, B ;
DUTARTRE, R ;
FIGUERAS, F .
MICROPOROUS MATERIALS, 1994, 2 (06) :525-535
[6]   Photocatalytic properties of titania pillared clays by different drying methods [J].
Ding, Z ;
Zhu, HY ;
Lu, GQ ;
Greenfield, PF .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1999, 209 (01) :193-199
[7]   Efficient dihydroxylation of naphthalene on photoirradiated rutile TiO2 powder in solution containing hydrogen peroxide [J].
Jia, JG ;
Ohno, T ;
Matsumura, M .
CHEMISTRY LETTERS, 2000, (08) :908-909
[8]   Synthesis and photocatalytic activity of titania pillared clays [J].
Kaneko, T ;
Shimotsuma, H ;
Kajikawa, M ;
Hatamachi, T ;
Kodama, T ;
Kitayama, Y .
JOURNAL OF POROUS MATERIALS, 2001, 8 (04) :295-301
[9]   Synthesis of titania pillared mica in aqueous solution of acetic acid [J].
Kaneko, T ;
Fujii, M ;
Kodama, T ;
Kitayama, Y .
JOURNAL OF POROUS MATERIALS, 2001, 8 (02) :99-109
[10]   Synthesis of titania pillared saponite in aqueous solution of acetic acid [J].
Kitayama, Y ;
Kodama, T ;
Abe, M ;
Shimotsuma, H ;
Matsuda, Y .
JOURNAL OF POROUS MATERIALS, 1998, 5 (02) :121-126