Anomalous Raman phenomenon of CuCrS2

被引：11

作者：

Abramova, G. M. ^{[1
]}

Petrakovskiy, G. A. ^{[1
]}

Vtyurin, A. N. ^{[1
]}

Rasch, J. C. E. ^{[2
]}

Krylov, A. S. ^{[1
]}

Gerasimova, J. V. ^{[1
]}

Velikanov, D. A. ^{[1
]}

Boehm, V. M. ^{[2
]}

Sokolov, V. ^{[3
]}

机构：

[1] Russian Acad Sci, Siberian Branch, Kirensky Inst Phys, Krasnoyarsk 660036, Russia

[2] Inst Max von Laue Paul Langevin, Grenoble 9, France

[3] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk 630090, Russia

来源：

JOURNAL OF RAMAN SPECTROSCOPY | 2010年 / 41卷 / 12期

关键词：

layered sulfides; Raman spectroscopy; infrared spectroscopy; technology;

D O I：

10.1002/jrs.2630

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

Structural dynamics of the layered CuCrS2 is investigated for the first time by using the Raman scattering method in 78-295 K temperature range on the samples synthesized by different methods. The Raman and IR spectra of CuCrS2 were simulated within the valence force field model with the LADY program. The results presented indicate that the lattice dynamics of CuCrS2 depends strongly on the real microstructure and technology of the sample preparation. The anomalous splitting of the A(1) phonon mode might be due to presence of the alpha- and beta-domains. Copyright (C) 2010 John Wiley & Sons, Ltd.

引用

页码：1775 / 1778

页数：4

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