Controlled assembly based on multibridging thiolate ligands: New polymeric silver(I) complexes with one-dimensional chain and three-dimensional network structures

被引：98

作者：

Hong, MC ^{[1
]}

Su, WP ^{[1
]}

Cao, R ^{[1
]}

Zhang, WJ ^{[1
]}

Li, JX ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China

来源：

INORGANIC CHEMISTRY | 1999年 / 38卷 / 03期

关键词：

D O I：

10.1021/ic980367t

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The polymeric silver(I) thiolate complexes of [Ag-6(mu(3)-SC5H4N)(4)(mu(4)-SC5H4N)(2)](n) (1) and [Ag(mu(2)-SC5H4NH)Cl](n) (2) have been prepared from the controlled assembling reactions of silver chloride and 2-mercaptopyridine. X-ray diffraction analyses show that I has one-dimensional chain structure and 2 has three-dimensional network structure. The coordination geometry of each Ag(I) in 1 is a distorted tetrahedron of S3N, while that in 2 is a tetrahedron of S2Cl2. The sulfur atom of the thiolate ligand in I exhibits either mu(3) or mu(4) bridge linking three or four silver centers.

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页码：600 / +

页数：4

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