An M-H center dot center dot center dot H-C hydrogen bonding interaction

被引：59

作者：

Richardson, TB

Koetzle, TF

Crabtree, RH

机构：

[1] YALE UNIV,DEPT CHEM,NEW HAVEN,CT 06520

[2] BROOKHAVEN NATL LAB,DEPT CHEM,UPTON,NY 11973

来源：

INORGANICA CHIMICA ACTA | 1996年 / 250卷 / 1-2期

关键词：

metal hydride complexes; aryl phosphine complexes; metal hydrogen carbon hydrogen interaction;

D O I：

10.1016/S0020-1693(96)05212-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Study of several X-ray and neutron diffraction crystal structures of aryl phosphine hydride complexes shows that abnormally close CH...HM contacts (1.6-2.1 Angstrom) commonly occur between the arene CH bonds and the hydride. The data suggest that weak CH...HM hydrogen bonds are involved, resembling those we have previously characterized for the NH...HM case. Based on these results, a new mechanism is suggested for cyclometallation.

引用

收藏

页码：69 / 73

页数：5

相关论文

共 33 条

[1] REACTION OF H-2 WITH IRHCL2P2 (P = P(I)PR(3) OR P(T)BU2PH) - STEREOELECTRONIC CONTROL OF THE STABILITY OF MOLECULAR H-2 TRANSITION-METAL COMPLEXES [J].

ALBINATI, A ;

BAKHMUTOV, VI ;

CAULTON, KG ;

CLOT, E ;

ECKERT, J ;

EISENSTEIN, O ;

GUSEV, DG ;

GRUSHIN, VV ;

HAUGER, BE ;

KLOOSTER, WT ;

KOETZLE, TF ;

MCMULLAN, RK ;

OLOUGHLIN, TJ ;

PELISSIER, M ;

RICCI, JS ;

SIGALAS, MP ;

VYMENITS, AB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (16) :7300-7312

[2]

Allen F.H., 1993, CHEM AUTOMAT NEWS, V8, P31

[3] SOME 10-VERTEX NIDO-METALLABORANES - OXIDATIVE INSERTION OF IRIDIUM(I) AND RHODIUM(I) INTO THE ARACHNO-NONABORATE ANION, [B9H14]-, AND THE CRYSTAL AND MOLECULAR-STRUCTURE OF 6-HYDRIDO-6,6-BIS(TRIPHENYLPHOSPHINE)-NIDO-6-IRIDADECABORANE, [(HLR(III)B9H13)(PPH3)2 [J].

BOOCOCK, SK ;

BOULD, J ;

GREENWOOD, NN ;

KENNEDY, JD ;

MCDONALD, WS .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1982, (04) :713-719

[4] QUANTITATIVE ORTHO-CYCLOBORONATION OF P-PHENYL GROUPS IN METALLABORANE CHEMISTRY AND THE CRYSTAL AND MOLECULAR-STRUCTURE OF THE NOVEL ISO-CLOSO-TEN-VERTEX METALLABORANE [1,1,1-H(PPH3)(PH2P-ORTHO-C6H4)-ISO-CLOSO-(1-IRB9H8-2-) [J].

BOULD, J ;

GREENWOOD, NN ;

KENNEDY, JD ;

MCDONALD, WS .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1982, (08) :465-467

[5] SIMULTANEOUS PHOTODISSOCIATION OF H2 AND PME2PH FROM OSH4(PME2PH)3 - PRODUCTION OF DIMERIC AND PARAMAGNETIC OSMIUM POLYHYDRIDES [J].

BRUNO, JW ;

HUFFMAN, JC ;

GREEN, MA ;

ZUBKOWSKI, JD ;

HATFIELD, WE ;

CAULTON, KG .

ORGANOMETALLICS, 1990, 9 (09) :2556-2567

[6] SYNTHESIS AND STUDY OF THE RUTHENIUM SILENE COMPLEXES (ETA(5)-C5ME5)(PR3)RUH(ETA(2)-CH2=SIR'2) (R = (I)PR, CY R' = ME, PH) [J].

CAMPION, BK ;

HEYN, RH ;

TILLEY, TD ;

RHEINGOLD, AL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (13) :5527-5537

[7] N-H ACTIVATION .1. OXIDATIVE ADDITION OF AMMONIA TO IRIDIUM(I) - ISOLATION, STRUCTURAL CHARACTERIZATION, AND REACTIVITY OF AMIDOIRIDIUM HYDRIDES [J].

CASALNUOVO, AL ;

CALABRESE, JC ;

MILSTEIN, D .

INORGANIC CHEMISTRY, 1987, 26 (07) :971-973

[8] THE REACTION OF (PPRI3)2CL2H2IR WITH PHOSPHINES - CRYSTAL AND MOLECULAR-STRUCTURES OF MER-CIS-(PME2PH)2(PPRI3)-CIS-CL2HIRIII AND MER-CIS-(PME2PH)2(PPRI3)-TRANS-CL2HIRIII [J].

DITZEL, EJ ;

ROBERTSON, GB .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1993, 46 (04) :529-545

[9] PENTAHYDRIDORHENIUM - CRYSTAL AND MOLECULAR-STRUCTURE OF REH5(PMEPH2)3 [J].

EMGE, TJ ;

KOETZLE, TF ;

BRUNO, JW ;

CAULTON, KG .

INORGANIC CHEMISTRY, 1984, 23 (24) :4012-4017

[10] INTERACTION BETWEEN [(ETA(5)-C5ME5)2OSH]+PF6- AND NITROGEN OR OXYGEN BASES - HYDROGEN-BONDS OF THE TYPE [OSH]+ ... B [J].

EPSTEIN, LM ;

SHUBINA, ES ;

KRYLOV, AN ;

KREINDLIN, AZ ;

RYBINSKAYA, MI .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 447 (02) :277-280

← 1 2 3 4 →