Composition and structure of agents responsible for development of water repellency in soils following oil contamination

被引：28

作者：

Litvina, M ^{[1
]}

Todoruk, TR ^{[1
]}

Langford, CH ^{[1
]}

机构：

[1] Univ Calgary, Dept Chem, Calgary, AB T2N 1N4, Canada

来源：

ENVIRONMENTAL SCIENCE & TECHNOLOGY | 2003年 / 37卷 / 13期

关键词：

D O I：

10.1021/es026296l

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

Soil from the Ellerslie site of experimental oil contamination in Alberta developed water repellency some years after initial remediation. The water-repellent soils were compared to clean soils and contaminated but wettable soils by solid-state nuclear magnetic resonance (NMR). The effects of extraction with CH2Cl2 (for petroleum hydrocarbons), NaOH (for natural organic matter), and 2-propanol/ammonia (IPA/NH3) on wettability were evaluated by the molarity of the ethanol droplet (MED) test. Soil extracts and whole soils, after extraction, were examined using NMR and Fourier transform infrared spectroscopy (FTIR). On the basis of the structure-MED correlations, a model of a thin-layer natural organic matter-petroleum products complex formed under strong drying conditions is proposed to account for the development of water repellency. Studies of two similar soils from accidental oil spills are supportive.

引用

页码：2883 / 2888

页数：6

共 24 条

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