A biomimetic model of the electron transfer between P680 and the TyrZ-His190 pair of PSII

被引：85

作者：

Lachaud, T

Quaranta, A

Pellegrin, Y

Dorlet, P

Charlot, MF

Un, S

Leibl, W

Aukauloo, A

机构：

[1] Univ Paris 11, Chim Inorgan Lab, F-91405 Orsay, France

[2] CEA Saclay, Serv Bioenerget, F-91191 Gif Sur Yvette, France

[3] Museum Natl Hist Nat, CNRS, UMR 5154, Lab Chim & Biochim Subst Nat,USM 0502, F-75005 Paris, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 10期

关键词：

artificial photosynthesis; biomimetic synthesis; phenoxyl radicals; photochemistry; ruthenium;

D O I：

10.1002/anie.200461948

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Artificial photosynthesis: The first photoelectron trade between P 680 and the TyrZ-His190 pair of Photosystem II was modeled by a ruthenium(II) trisbipyridine type complex that contains a phenol hydrogen atom bonded to an imidazole group. The photogenerated phenoxyl radical has been characterized. This opens up the way for a more complete biomimetic model of Photosystem II. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：1536 / 1540

页数：5

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